TV I admit is limited, though V does have Inara from Firefly being all evil and kick-ass and that late night creepy TV show 'Afterlife?'.
Movies however wow just wow. Alice in Wonderland, Shrek 4, Inkheart, Sherlock Holmes (in addition to amazing slash), Zombieland, Wall-ie, Inglorious Bastards (Okay they had one for the win and one fail, but still the one that wins, really wins) and lots of others.